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Updated: Aug 3, 2026

Highly Stereoselective Synthesis of 1,6-Ketoesters Mediated by Ionic Liquids: A Three-component Reaction Enabling Rapid Access to a New Class of Low Molecular Weight Gelators
06:31

Highly Stereoselective Synthesis of 1,6-Ketoesters Mediated by Ionic Liquids: A Three-component Reaction Enabling Rapid Access to a New Class of Low Molecular Weight Gelators

Published on: November 27, 2015

非対称なclaisen再配置は,触媒非対称のDi (((アルリル) エーテル合成によって可能になりました

Scott G Nelson1, Kan Wang

  • 1Department of Chemistry, University of Pittsburgh, Pennsylvania 15260, USA. sgnelson@pitt.edu

Journal of the American Chemical Society
|March 30, 2006
PubMed
まとめ

この研究では,高効率な非対称アリファティック・クライゼン再編成のために,触媒的非対称合成とオレフィン異体化-クライゼン再編成を組み合わせた2段階の方法が紹介されています. このアプローチは,高度にステレオ制御された2,3-非置換の4-ペンテナル派生子を生成し,その合成的有用性を示しています.

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Intramolecular Claisen Condensation of Dicarboxylic Esters: Dieckmann Cyclization

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[3,3] Sigmatropic Rearrangement of Allyl Vinyl Ethers: Claisen Rearrangement

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