アミノ酸を含有するROMPポリマーは,ステレオレギュラーな骨格を持つ
Jae Chul Lee1, Kathlyn A Parker, Nicole S Sampson
1Department of Chemistry, Stony Brook University, Stony Brook, New York 11794-3400, USA.
Journal of the American Chemical Society
|April 6, 2006
まとめ
ルテニウム触媒によるリング開きポリメリゼーションは,制御されたポリブタディエンのバックボーンを持つ高度に秩序付けられたポリマーを生成します. これらのポリマーは低ポリ分散性を示し,先進的なアプリケーションに適した生体ポリメリゼーションプロセスを示しています.
科学分野:
- ポリマー化学のポリマー化学について
- オーガニック・シンセシス オーガニック・シンセシス
- マテリアルサイエンス 材料科学
背景:
- リング開きポリメリゼーション (ROMP) は,ポリマー合成のための多用途な方法です.
- 高いステレオレギュラリティと制御されたポリマーアーキテクチャを達成することは,ROMPにおける課題です.
- 機能化されたポリブタディエンの骨格は,様々な材料の用途に望ましい.
研究 の 目的:
- ROMPを使用して,翻訳的に不変で,頭から尾まで順序付けられたポリマーを合成するために.
- ポリメリゼーションのステレオ化学的結果と生命特性を調査する.
- ステレオレギュラー,機能化された鎖を必要とするアプリケーションにおけるこれらのポリマーの可能性を調査する.
主な方法:
- 1-サイクロブテンカルボニルグリシンメチルエステルのルテニウム触媒リング開きポリメリゼーション (ROMP).
- 構造,ステレオ化学,分子量分布を決定する技術を用いたポリマー製品の特徴化.
- ポリマー骨格内のオレフィン幾何学とステレオセンターの分析.
主要な成果:
- 翻訳的に不変で,頭から尾まで順番に並ぶポリマーを成功して合成した.
- ポリブタディエンの骨格は,E-三置換オレフィンのみを含み,ステレオセンターは欠けていた.
- ポリマーは低ポリ分散率 (1.21.6) を示し,生きたポリメリゼーションプロセスを示した.
- 1-サイクロブテンカルボキシアミド由来ポリマーは,機能化の有望性を示した.
結論:
- ルテニウムで触媒化されたROMPは,ポリマーの構造とステレオ化学を正確に制御します.
- 合成されたポリマーは高度に順序付けられ,よく定義されたポリブタディエンの骨格を持っています.
- これらのポリマーは,極性リガンドを持つステレオレギュラーチェーンを必要とするアプリケーションに適しています.
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