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Updated: Aug 1, 2026

Unraveling Entropic Rate Acceleration Induced by Solvent Dynamics in Membrane Enzymes
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陽子トンネリングが支配する酵素反応の原子的記述

Laura Masgrau1, Anna Roujeinikova, Linus O Johannissen

  • 1Manchester Interdisciplinary Biocentre, University of Manchester, Jackson's Mill, Post Office Box 88, Manchester M60 1QD, UK.

Science (New York, N.Y.)
|April 15, 2006
PubMed
まとめ

酵素触媒には,トリプトアミンの酸化のような反応に不可欠な量子効果である陽子トンネル化が含まれています. この研究は,長距離ではなく,短距離の動きが,主にアロマティック・アミン・デヒドロゲネーゼにおけるこの陽子の移転を促進することを明らかにしています.

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