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Updated: Jul 11, 2026

Amide Coupling Reaction for the Synthesis of Bispyridine-based Ligands and Their Complexation to Platinum as Dinuclear Anticancer Agents
07:20

Amide Coupling Reaction for the Synthesis of Bispyridine-based Ligands and Their Complexation to Platinum as Dinuclear Anticancer Agents

Published on: May 28, 2014

PtとPdはdibenz[a,c]anthraceneのエッジに1,4シフトしている

Anupam Singh1, Paul R Sharp

  • 1Department of Chemistry, University of Missouri, Columbia, Missouri 65211, USA.

Journal of the American Chemical Society
|May 4, 2006
PubMed
まとめ

プラチナとパラジウム複合体をディベンズ[a,c]アントラセンのリガンドで加熱すると,炭素結合金属の1,4シフトが誘発されます. この反応は,プラチナの場合より速く,極性中間物質を含み,酸性経路を避けます.

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