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Updated: Jul 24, 2026

Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene
09:45

Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene

Published on: March 20, 2017

ヴィニルサイクロプロパンとパイシステムの [5 + 2] サイクル添加反応の非対称な触媒

Paul A Wender1, Lars O Haustedt, Jaehong Lim

  • 1Department of Chemistry, Stanford University, Stanford, California 94305, USA. wenderp@stanford.edu

Journal of the American Chemical Society
|May 11, 2006
PubMed
まとめ

研究者らは,金属触媒 [5 + 2] サイクロアディションのための高度に選択的なロジウム触媒を開発しました. これらの触媒は,ビニルcyclopropanes (VCPs) とpi-systemsを効率的に高エナティオメア過剰を持つ複雑な分子に変換します.

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