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ピリジンの室温環開きメタテシスは,一時的なTi[トリプル結合]C結合によって行われる

Brad C Bailey1, Hongjun Fan, John C Huffman

  • 1Department of Chemistry, Molecular Structure Center and School of Informatics, Indiana University, Bloomington, IN 47405, USA.

Journal of the American Chemical Society
|May 25, 2006
PubMed
まとめ

暫定的なチタンのアルキリジンの複合体は,室温でピリジンのようにN-ヘテロサイクルを割る. この反応は環開くメタテシス経路を経由して進行し,重要な炭素-窒素結合を断ち切る.

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