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Updated: Aug 8, 2026

A Two-Step Protocol for Umpolung Functionalization of Ketones Via Enolonium Species
08:12

A Two-Step Protocol for Umpolung Functionalization of Ketones Via Enolonium Species

Published on: August 16, 2018

ケトイミネスの触媒エナチオセレクティブアリレーション

Reiko Wada1, Tomoyuki Shibuguchi, Sae Makino

  • 1Graduate School of Pharmaceutical Sciences, The University of Tokyo, Tokyo 113-0033, Japan.

Journal of the American Chemical Society
|June 8, 2006
PubMed
まとめ

新しい触媒的方法により,銅フッ化物 (CuF) とアルリルボロン酸ピナコールエステルを使用してケトイミンのアリレーションが可能になりました. このアプローチは高いエナチオ選択性を達成し,価値ある化合物の非対称合成の道を開く.

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