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Updated: Jul 10, 2026

Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
19:58

Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions

Published on: July 30, 2017

アルキニルカルベンの複合中間物質のルテニウム触媒 [1,n] - メタロトロピクシフト (n = 3, 5)

Kouichi Ohe1, Michinobu Fujita, Hideyuki Matsumoto

  • 1Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan. ohe@scl.kyoto-u.ac.jp

Journal of the American Chemical Society
|July 20, 2006
PubMed
まとめ

ルテニウム触媒はアルキンをイソメリ化し,ダイインとトリインをダイニンとダイネディニンに変換する. この反応は,アルキニルカルベンの複合体を含む[1,n]-メタロトロピクシフトメカニズムで進行する.

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Catalysis02:50

Catalysis

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Formation of Complex Ions03:45

Formation of Complex Ions

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Metal-Ligand Bonds

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In these complexes, transition metals form coordinate covalent bonds, a kind of Lewis acid-base interaction in which both of the electrons in the bond are contributed by a donor (Lewis base) to an electron acceptor (Lewis acid). The Lewis acid in...
Properties of Organometallic Compounds01:23

Properties of Organometallic Compounds

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Complexation Equilibria: Factors Influencing Stability of Complexes

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Heterogeneous Catalysis

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