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アルコールからアルケニル基のチタン媒介移転による二次アミンの合成

Balasubramanian Ramanathan1, Aaron L Odom

  • 1Department of Chemistry, Michigan State University, East Lansing, Michigan 48824, USA.

Journal of the American Chemical Society
|July 20, 2006
PubMed
まとめ

チタンアミド複合体は,アルコールからアミンへの選択的アリル転移を促進し,提案されたサイクル添加機構を通じて二次アリルアミンを形成します. この方法により,ホモアリルアルコールから複雑なスパイロサイクリックアミンの合成も可能になります.

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