端末アルコキソリガンドと協調オレフィン間の炭素-酸素結合形成. ロジウムアルコキシドにオレフィン挿入の証拠

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Updated: Jul 8, 2026

Synthesis of Antiviral Tetrahydrocarbazole Derivatives by Photochemical and Acid-catalyzed C-H Functionalization via Intermediate Peroxides (CHIPS)
06:34

Synthesis of Antiviral Tetrahydrocarbazole Derivatives by Photochemical and Acid-catalyzed C-H Functionalization via Intermediate Peroxides (CHIPS)

Published on: June 20, 2014

Pinjing Zhao1, Christopher D Incarvito, John F Hartwig

  • 1Department of Chemistry, Yale University, P.O. Box 208107, New Haven, Connecticut 06520-8107, USA.

Journal of the American Chemical Society
|July 27, 2006
PubMed
まとめ

ロジウム ((I) アルコシドは,オレフィン調整により分解され,代用されたテトラヒドロフーランやアリル複合体を形成する. この反応性は,有機金属変換とヘテロサイクルの合成のための新しい経路を明らかにします.

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