軌道上退廃した有機リドックスセンターを持つ混合バレンスのシステムの新しいクラス. ヘクサレニウム分子プリズマに基づく例

Peter H Dinolfo1, Veaceslav Coropceanu, Jean-Luc Brédas

  • 1Department of Chemistry, Northwestern University, Evanston, IL 60208, USA.

PubMed
まとめ

本研究では,新しい超分子プリズマ複合体におけるリガンド中心混合バレンスの特性 (LCMV) を調査しています. 研究者らは,これらの異常な混合バレンスの化合物 (MV) の内部でユニークな電子相互作用と電荷再分配を発見しました.

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