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Updated: Apr 22, 2026

Tuning the Acidity of Pt/ CNTs Catalysts for Hydrodeoxygenation of Diphenyl Ether
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セレクティブプロピレンオリゴメリゼーションのためのハフノセンの触媒:β-メチル移転による4-メチル-1-ペンテンの効率的な合成

Yasuhiko Suzuki1, Takahiro Yasumoto, Kazushi Mashima

  • 1Institute of Inorganic Chemistry, RWTH Aachen University, Landoltweg 1, D-52074 Aachen, Germany.

Journal of the American Chemical Society
|September 28, 2006
PubMed
まとめ

ハフノセンの複合体は,プロピレン二酸化を4-メチル-1-ペンテンに効率的に触媒化し,リガンド置換剤によって選択性が影響されます. ステリカルに阻害されたリガンドと特定の反応条件により,4メチル-1-ペンテン生成が最適化され,他の複合体はポリメリゼーションまたは急速な無効化を示します.

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