化学選択的核性アリレーションとアルデヒドの単段階の酸化エステル化には,シロキサンとパラジウム・フォスフィノ酸を反応スイッチとして使用する

Rachel Lerebours1, Christian Wolf

  • 1Department of Chemistry, Georgetown University, Washington, DC 20057, USA.

まとめ

アルデヒドとシロキサンは,パラジウム触媒による酸化エステル化を使用してメチルエステルに変換することができます. また,二次アルコールは,触媒なしで,テトラブチラモニウムフッ素が促進するアリレーションによって形成されます.

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