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Updated: Jul 19, 2026

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions
11:44

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions

Published on: March 20, 2014

パラジウム触媒による非対称 [3 + 2] トリメチレンメタンサイクロアディション反応

Barry M Trost1, James P Stambuli, Steven M Silverman

  • 1Department of Chemistry, Stanford University, Stanford, CA 94305-5080, USA. bmtrost@stanford.edu

Journal of the American Chemical Society
|October 13, 2006
PubMed
まとめ

この研究では,機能化されたサイクロペンタンを合成するために,パラジウム触媒化された非対称トリメチレンメタン (TMM) サイクロアディションを提示しています. この反応は,高収量と優れたエナチオ選択性を提供し,貴重なキラル化合物への直接的な経路を提供します.

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