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Updated: Jul 10, 2026

Isolating Free Carbenes, their Mixed Dimers and Organic Radicals
10:44

Isolating Free Carbenes, their Mixed Dimers and Organic Radicals

Published on: April 19, 2019

交代結合は,形状的に制約されたポリラジカル・スキャフォルドで,スルー・ボンドとスルー・スペースを媒介する: カリックス[4]アレン・窒素・テトララジカルとディラジカル・スキャフォルド

Andrzej Rajca1, Sumit Mukherjee, Maren Pink

  • 1Department of Chemistry, University of Nebraska, Lincoln, NE 68588-0304, USA. arajca1@unl.edu

Journal of the American Chemical Society
|October 13, 2006
PubMed
まとめ

合成されたカリックス[4]アレンポリラジカルは,磁気交換結合の構成的依存性を明らかにする. トゥース・ボンド・カップリングはコーンでは鉄磁性であり,1,3変形では反鉄磁性であり,トゥース・スペース・カップリングは両方とも反鉄磁性である.

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