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Updated: Jul 9, 2026

Targeted Antibody Blocking by a Dual-Functional Conjugate of Antigenic Peptide and Fc-III Mimetics (DCAF)
09:39

Targeted Antibody Blocking by a Dual-Functional Conjugate of Antigenic Peptide and Fc-III Mimetics (DCAF)

Published on: September 17, 2019

トリアリル (テトラヒドロフラン) アルミニウム反応剤によるアルデヒドへのアリレーションのための非常に効率的なエナンチオセレクティブチタニウム ((IV) - ((R) -H8-BINOLATE触媒である

Kuo-Hui Wu1, Han-Mou Gau

  • 1Department of Chemistry, National Chung-Hsing University, Taichung, Taiwan 402.

Journal of the American Chemical Society
|November 16, 2006
PubMed
まとめ

新しいチタン触媒反応は,アルミニウム反応剤とさまざまなアルデヒドからキラルダイアリルメタノールを効率的に合成します. この方法では,価値ある1 - アリルプロパルギルアルコールを含む様々な製品に対して高いエナンチオセレクティビティが得られます.

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Optimization of Radiochemical Reactions using Droplet Arrays10:54

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Metal-Ligand Bonds

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All meta-directing substituents are deactivating groups. These substituents withdraw electrons from the aromatic ring, making the ring less reactive toward electrophilic substitution. For example, the nitration of nitrobenzene is 100,000 times slower than that of benzene because of the deactivating effect of the nitro group. The first step in an electrophilic aromatic substitution is the addition of an electrophile to form a resonance-stabilized carbocation. The energy diagrams for the...
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Heterogeneous Catalysis

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