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Updated: Jul 18, 2026

Thermochemical Studies of Ni(II) and Zn(II) Ternary Complexes Using Ion Mobility-Mass Spectrometry
16:11

Thermochemical Studies of Ni(II) and Zn(II) Ternary Complexes Using Ion Mobility-Mass Spectrometry

Published on: June 8, 2022

ニッケルによる分子間アレンC-H活性化 (II)

Lan-Chang Liang1, Pin-Shu Chien, Yu-Lun Huang

  • 1Department of Chemistry and Center for Nanoscience & Nanotechnology, National Sun Yat-sen University, Kaohsiung 80424, Taiwan. lcliang@mail.nsysu.edu.tw

Journal of the American Chemical Society
|December 7, 2006
PubMed
まとめ

この研究では,軽度な条件下でニッケル触媒化された分子間アレンC-Hの活性化が示されています. 安価なニッケル (ニッケルII) 複合体は高い反応性を示し,貴金属触媒の経済的代替品を提供している.

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Catalysis02:50

Catalysis

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Reduction of Alkynes to cis-Alkenes: Catalytic Hydrogenation

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Like alkenes, alkynes can be reduced to alkanes in the presence of transition metal catalysts such as Pt, Pd, or Ni. The reaction involves two sequential syn additions of hydrogen via a cis-alkene intermediate.
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Reduction of Alkenes: Asymmetric Catalytic Hydrogenation

Catalytic hydrogenation of alkenes is a transition-metal catalyzed reduction of the double bond using molecular hydrogen to give alkanes. The mode of hydrogen addition follows syn stereochemistry.
The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
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Reduction of Alkenes: Catalytic Hydrogenation

Alkenes undergo reduction by the addition of molecular hydrogen to give alkanes. Because the process generally occurs in the presence of a transition-metal catalyst, the reaction is called catalytic hydrogenation.
Metals like palladium, platinum, and nickel are commonly used in their solid forms — fine powder on an inert surface. As these catalysts remain insoluble in the reaction mixture, they are referred to as heterogeneous catalysts.
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ortho–para-Directing Activators: –CH3, –OH, –⁠NH2, –OCH3

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Structural Isomerism

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