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Updated: Jul 18, 2026

Synthesis of Hypervalent Iodonium Alkynyl Triflates for the Application of Generating Cyanocarbenes
12:27

Synthesis of Hypervalent Iodonium Alkynyl Triflates for the Application of Generating Cyanocarbenes

Published on: September 8, 2013

グリオキサラゼI型半酸エセタルイソメリゼーション反応性,単核ニオニオニオニオニオニオニオニオニオニオニオニオニオニオニオニオニオニオニオニオニオニオニオニオニオニオニオニオニオニオニオニオニオニオニオニオニオニオニオニオニオニオニオニ

Katarzyna Rudzka1, Atta M Arif, Lisa M Berreau

  • 1Department of Chemistry and Biochemistry, Utah State University, Logan, UT 84322-0300, USA.

Journal of the American Chemical Society
|December 21, 2006
PubMed
まとめ

新しいニッケル (ニッケル) 複合体は,E. coliのグリオキサラーゼI活性を模倣して,ヘミチオアセタルイソメリゼーションを触媒化する. このデプロトン化アミド複合体は選択的反応性を示し,生物学的金属イオン触媒の洞察を提供している.

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Aldehydes and Ketones with Alcohols: Hemiacetal Formation

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