中間物質が移行状態になるのはいつですか? (S) - 1 - 3 - ニトロフェニル) エチルトシラートの溶解中に競争するラセミゼーションなしに退化性イソメリゼーション

Yutaka Tsuji1, John P Richard

  • 1Department of Biochemistry and Applied Chemistry, Kurume National College of Technology, Komorinomachi, Kurume 830-8555, Japan.

PubMed
まとめ

溶解中に (S) - 1 - 3 - ニトロフェニル) エチルトシラートのキラル純度が監視されました. アイソメリゼーションは,一般的なイオンペア中間物質を回避する経路を経由して発生し,溶解の段階的なプレアソシエーションメカニズムを示唆しています.

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