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Updated: Jun 29, 2026

Millifluidics for Chemical Synthesis and Time-resolved Mechanistic Studies
12:55

Millifluidics for Chemical Synthesis and Time-resolved Mechanistic Studies

Published on: November 28, 2013

遅い金属の中心間の超高速および超遅い酸素原子移転反応

Kevin C Fortner1, David S Laitar, John Muldoon

  • 1Department of Chemistry and Biochemistry, 251 Nieuwland Science Hall, University of Notre Dame, Notre Dame, Indiana 46556-5670, USA.

Journal of the American Chemical Society
|January 18, 2007
PubMed
まとめ

オキシトリメシチリリジウム ((V)) とイリジウム ((III)) 複合体は,室温で酸素原子を素早く移動する. このユニークな反応性により,イリジウムは,より遅いオスミウム類似体とは異なり,触媒的酸化のためにダイオキシゲンを活性化することができます.

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