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Updated: Jun 13, 2026

Thermochemical Studies of Ni(II) and Zn(II) Ternary Complexes Using Ion Mobility-Mass Spectrometry
16:11

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A.T.やG.Cの塩基対は,安定性が向上しているのでしょうか? 現象学的分析と初期計算を用いて,CH...O相互作用と二次相互作用の塩基対安定性への影響を定量化

Jordan R Quinn1, Steven C Zimmerman, Janet E Del Bene

  • 1Department of Chemistry, Roger Adams Laboratory, University of Illinois, 600 South Mathews Avenue, Urbana, Illinois 61801, USA.

Journal of the American Chemical Society
|January 25, 2007
PubMed
まとめ

アデニン-チミン (A.T) 塩基対は,CH...O相互作用により安定性が向上し,約 2-2.5 kcal mol-1. 1 を貢献しています. この相互作用はまた,AT塩基対におけるワトソン・クリックの幾何学よりもフーグスティーンを好む.

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