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Updated: Jul 10, 2026

Synthesis of Antiviral Tetrahydrocarbazole Derivatives by Photochemical and Acid-catalyzed C-H Functionalization via Intermediate Peroxides (CHIPS)
06:34

Synthesis of Antiviral Tetrahydrocarbazole Derivatives by Photochemical and Acid-catalyzed C-H Functionalization via Intermediate Peroxides (CHIPS)

Published on: June 20, 2014

トリプレット1,3-ディフェニルプロピニリデン (Ph-C-C-C-Ph)

Jeffrey T DePinto1, Wendy A deProphetis, Jessica L Menke

  • 1Department of Chemistry, University of Wisconsin-Madison, 1101 University Avenue, Madison, Wisconsin 53706-1396, USA.

Journal of the American Chemical Society
|February 7, 2007
PubMed
まとめ

1,3-ディフェニルプロピニルプロピンの光分解により,三重の1,3-ディフェニルプロピニリデンが生成され,これは1,3-アレーンの二基である. このダイラジカルは,ダイフェニルチクロプロペニリデンへの光化学的サイクル化を経て,可逆的なカルベンの化学性を示します.

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