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プライマリアミンと二次カルボキシアミドの間のTiIV媒介反応:アミジン形成とトランスアミデーションの比較

Denis A Kissounko1, Justin M Hoerter, Ilia A Guzei

  • 1Department of Chemistry, University of Wisconsin-Madison, 1101 University Avenue, Madison, Wisconsin 53706, USA.

Journal of the American Chemical Society
|February 8, 2007
PubMed
まとめ

タイタニウム (IV) 複合体は,アミンとカルボキシアミドの間の反応を媒介し,アミジンまたはトランスアミデーション製品を生成します. 特定のチタン (((IV)) 複合体と反応条件が結果を決定し,触媒Ti (((NMe2) 4が選択的トランスアミデーションを好む.

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