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関連する概念動画

Hydrogen Bonds00:26

Hydrogen Bonds

Hydrogen BondsHydrogen bonds are weak attractions between atoms that have formed other chemical bonds. One of these atoms is electronegative, like oxygen, and has a partial negative charge. The other is a hydrogen atom that has bonded with another electronegative atom and has a partial positive charge.Hydrogen Bonds Control the World!Because hydrogen has very weak electronegativity when it binds with a strongly electronegative atom, such as oxygen or nitrogen, electrons in the bond are...
Bond Energies and Bond Lengths02:49

Bond Energies and Bond Lengths

Stable molecules exist because covalent bonds hold the atoms together. The strength of a covalent bond is measured by the energy required to break it, that is, the energy necessary to separate the bonded atoms. Separating any pair of bonded atoms requires energy — the stronger a bond, the greater the energy required to break it.
Intermolecular Forces03:13

Intermolecular Forces

Atoms and molecules interact through bonds (or forces): intramolecular and intermolecular. The forces are electrostatic as they arise from interactions (attractive or repulsive) between charged species (permanent, partial, or temporary charges) and exist with varying strengths between ions, polar, nonpolar, and neutral molecules. The different types of intermolecular forces are ion–dipole, dipole–dipole, hydrogen bonds, and dispersion; among these, dipole–dipole, hydrogen bonds, and dispersion...
Intermolecular Forces03:13

Intermolecular Forces

Atoms and molecules interact through bonds (or forces): intramolecular and intermolecular. The forces are electrostatic as they arise from interactions (attractive or repulsive) between charged species (permanent, partial, or temporary charges) and exist with varying strengths between ions, polar, nonpolar, and neutral molecules. The different types of intermolecular forces are ion–dipole, dipole–dipole, hydrogen bonds, and dispersion; among these, dipole–dipole, hydrogen bonds, and dispersion...
Hydrogen Bonds01:04

Hydrogen Bonds

A hydrogen bond is formed when a weakly positive hydrogen atom already bonded to one electronegative atom (for example, the oxygen in the water molecule) is attracted to another electronegative atom from another polar molecule, such as water (H2O), hydrogen fluoride (HF), or ammonia (NH3). The huge electronegativity difference between the H atom (2.1) and the atom to which it is bonded (4.0 for an F atom, 3.5 for an O atom, or 3.0 for an N atom), combined with the very small size of an H atom...
The Electrical Double Layer01:30

The Electrical Double Layer

In the region where two bulk phases meet, an intricate electric charge distribution arises due to charge transfer, ion adsorption, molecular orientation, and charge distortion. This complex distribution is commonly referred to as the electrical double layer.When a solid electrode interfaces with ions in an electrolyte solution, the speed of electron transfer dictates the rates of oxidation and reduction. The electrode acquires a charge through the escape of atoms into the solution as cations or...

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関連する実験動画

Updated: Jul 11, 2026

Adhesion Frequency Assay for In Situ Kinetics Analysis of Cross-Junctional Molecular Interactions at the Cell-Cell Interface
13:22

Adhesion Frequency Assay for In Situ Kinetics Analysis of Cross-Junctional Molecular Interactions at the Cell-Cell Interface

Published on: November 2, 2011

分子結合における熱電性は,分子結合における熱電性である.

Pramod Reddy1, Sung-Yeon Jang, Rachel A Segalman

  • 1Applied Science and Technology Program, University of California, Berkeley, CA 94720, USA.

Science (New York, N.Y.)
|February 17, 2007
PubMed
まとめ

研究者らは,分子結合の熱電気的性質を測定した. 彼らは,金分子・金系におけるp型伝導性を発見し,分子熱電気エネルギー変換の扉を開いた.

科学分野:

  • 分子電子は分子電子である.
  • 凝縮物質物理学 凝縮物質物理学
  • ナノテクノロジー ナノテクノロジー

背景:

  • 熱電気材料は,熱を電気に変換する.
  • 分子結合は,調節可能な電子特性を提供します.
  • 分子システムにおける電荷輸送の理解は極めて重要です.

研究 の 目的:

  • 分子結合のシーベック係数を測定する.
  • 金-分子-金ヘテロ結合における電荷载体型を決定する.
  • 分子熱電気エネルギー変換の可能性を調査する.

主な方法:

  • 黄金の電極間のトラッピング分子 (BDT,ディベンゼンデチオール,トリベンゼンデチオール).
  • 電極に温度差を適用する.
  • 測定点 室温でのシーベック係数.

主要な成果:

  • 測定されたシーベック係数は, +8.7 μV/K (BDT), +12.9 μV/K (4,4'-二ベンゼンデチオール), +14.2 μV/K (4,4'-三ベンゼンデチオール) でした.
  • ポジティブなシーベック係数は,明確なp型 (穴) 伝導を示す.
  • オー・フェルミレベルは,BDTの最も高い分子軌道より1.2 eV高いと判定された.

さらに関連する動画

Spatial Separation of Molecular Conformers and Clusters
10:37

Spatial Separation of Molecular Conformers and Clusters

Published on: January 9, 2014

Molecular Entanglement and Electrospinnability of Biopolymers
07:59

Molecular Entanglement and Electrospinnability of Biopolymers

Published on: September 3, 2014

関連する実験動画

Last Updated: Jul 11, 2026

Adhesion Frequency Assay for In Situ Kinetics Analysis of Cross-Junctional Molecular Interactions at the Cell-Cell Interface
13:22

Adhesion Frequency Assay for In Situ Kinetics Analysis of Cross-Junctional Molecular Interactions at the Cell-Cell Interface

Published on: November 2, 2011

Spatial Separation of Molecular Conformers and Clusters
10:37

Spatial Separation of Molecular Conformers and Clusters

Published on: January 9, 2014

Molecular Entanglement and Electrospinnability of Biopolymers
07:59

Molecular Entanglement and Electrospinnability of Biopolymers

Published on: September 3, 2014

結論:

  • 分子結合は,熱電効果が顕著である.
  • 金分子・金系におけるp型伝導性が実証されている.
  • 分子熱電気エネルギーの採集と電子構造の研究の可能性を強調しています.