不飽和末端エポキシドとクロロヒドリンの内分子サイクロプロパネーション

David M Hodgson1, Ying Kit Chung, Irene Nuzzo

  • 1Department of Chemistry, University of Oxford, Chemistry Research Laboratory, Mansfield Road, Oxford, OX1 3TA, UK. david.hodgson@chem.ox.ac.uk

まとめ

リチウム2,2,6,6-テトラメチルピペリジド (LTMP) は,エポキシドのステレオ選択性サイクロプロパネーションを可能にし,バイサイクルアルコールを生成します. 2,2,6,6-テトラメチルピペリジン (TMP) を用いた触媒的方法は,これらの貴重な化合物のスケーラブルな合成を提供します.

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