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Updated: Jul 5, 2026

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions
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Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions

Published on: March 20, 2014

ダイアルキルビアリルフォスフィンの分子酸素による酸化に対する抵抗の裏付け

Timothy E Barder1, Stephen L Buchwald

  • 1Department of Chemistry, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, Massachusetts 02139, USA.

Journal of the American Chemical Society
|March 29, 2007
PubMed
まとめ

電子が豊富なダイアルキルビアリルホスフィンは,その構造により酸化に抵抗する. アルキル基と特定のビアリル基幹の位置は,パラジアム触媒によるクロスカップリング反応において極めて重要なこれらのリガンドを保護する.

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