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Updated: Jul 16, 2026

Protein Film Infrared Electrochemistry Demonstrated for Study of H2 Oxidation by a [NiFe] Hydrogenase
10:01

Protein Film Infrared Electrochemistry Demonstrated for Study of H2 Oxidation by a [NiFe] Hydrogenase

Published on: December 4, 2017

ヘム・ヒドロペロキシダースモデルによるO−O結合活性化のプロトン誘導リドックス制御

Jake D Soper1, Sergey V Kryatov, Elena V Rybak-Akimova

  • 1Department of Chemistry, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge Massachusetts 02139-4207, USA.

Journal of the American Chemical Society
|April 3, 2007
PubMed
まとめ

ハングマンメタルポルフィリン複合体は,酸化反応におけるO−O結合活性化を制御するために,陽子ドナー群を使用して,酵素活性部位を模倣する. この陽子制御は反応経路を決定し,触媒効率を高めます.

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