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Updated: Jul 16, 2026

Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
19:58

Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions

Published on: July 30, 2017

アリルからイミドイル・パラジウムへの移行過程は,分子内C-H活性化を含む

Jian Zhao1, Dawei Yue, Marino A Campo

  • 1Department of Chemistry, Iowa State University, Ames, Iowa 50011, USA.

Journal of the American Chemical Society
|April 3, 2007
PubMed
まとめ

新しいパラジウム移動とC-H活性化の方法により,フッ素-9-oneとキサンタン-9-oneの誘導体が生成されます. ユニークなオルガンパラジウム ((IV) ハイドリド中間物とデウテリウムラベルが,この二重合成メカニズムをサポートしています.

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