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Updated: May 4, 2026

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パラジウム触媒による非対称フォスフィネーション. エナチオセレクティビティの範囲,メカニズム,起源

Natalia F Blank1, Jillian R Moncarz, Tim J Brunker

  • 1Contribution from the 6128 Burke Laboratory, Department of Chemistry, Dartmouth College, Hanover, New Hampshire 03755, USA.

Journal of the American Chemical Society
|May 4, 2007
PubMed
まとめ

この研究では,キラルパラジウム触媒を使用して,エンアンチオインリッチド三次性フォスフィンを生成するための非対称クロスカップリング方法を開発しました. 立体的に阻害されたフォスフィン基板と電子が豊富なアリルヨーデッドは,最大88%の最も高いエナティオメリック過剰を生成しました.

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