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Updated: Jul 14, 2026

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions
11:44

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions

Published on: March 20, 2014

トリート・ブチルフォスフィン・プラチナ・パラジウムグループによる金属水化物複合体の活性化

Richard D Adams1, Burjor Captain, Eszter Trufan

  • 1Department of Chemistry and Biochemistry, University of South Carolina, Columbia, South Carolina 29208, USA. Adams@mail.chem.sc.edu

Journal of the American Chemical Society
|May 29, 2007
PubMed
まとめ

金属水化物HM(CO) 4SnPh3は,Mがオスミウム (Os) またはルテニウム (Ru) である場合,プラチナまたはパラジウム複合体の存在でフェニラセチレン (PhC2H) と反応する. この反応により,フェニラセチレンが金属ヒドリド結合に挿入され,新しい有機金属化合物が形成されます.

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