ボロン酸化物クラスターにおける主要な構造単位としてのボロニル:B(BO) 2−およびB(BO) 3−
Hua-Jin Zhai1, Si-Dian Li, Lai-Sheng Wang
1Department of Physics, Washington State University, Richland, WA 99354, USA.
Journal of the American Chemical Society
|July 12, 2007
まとめ
No abstract available in PubMed .
関連する概念動画
Covalent Bonding and Lewis Structures
Compared to ionic bonds, which results from the transfer of electrons between metallic and nonmetallic atoms, covalent bonds result from the mutual attraction of atoms for a “shared” pair of electrons.
Lewis Structures of Molecular Compounds and Polyatomic Ions
To draw Lewis structures for complicated molecules and molecular ions, it is helpful to follow a step-by-step procedure as outlined:
Exceptions to the Octet Rule
Many covalent molecules have central atoms that do not have eight electrons in their Lewis structures. These molecules fall into three categories:
Predicting Molecular Geometry
VSEPR Theory for Determination of Electron Pair Geometries
Hydroboration-Oxidation of Alkenes
In addition to the oxymercuration–demercuration method, which converts the alkenes to alcohols with Markovnikov orientation, a complementary hydroboration-oxidation method yields the anti-Markovnikov product. The hydroboration reaction, discovered in 1959 by H.C. Brown, involves the addition of a B–H bond of borane to an alkene giving an organoborane intermediate. The oxidation of this intermediate with basic hydrogen peroxide forms an alcohol.
Properties of Organometallic Compounds
Organometallic compounds are compounds that contain a carbon–metal bond. Carbon belongs to an organyl group like alkyl, aryl, allyl, or benzyl groups. The metal can be from Group I or Group II of the periodic table, a transition metal, or a semimetal.


