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バイブサニンEに対する合成努力において,紫外線補助 [4 + 2] サイクル添加のメカニズム研究が行われた

Joachim Nikolai1, Øystein Loe, Paulina M Dominiak

  • 1Department of Chemistry, University at Buffalo, The State University of New York, Buffalo, New York 14260-3000, USA.

Journal of the American Chemical Society
|August 19, 2007
PubMed
まとめ

この研究は,光化学的サイクル添加における異常なステレオ選択性を明らかにしています. 計算では,シス・トランス・イソメリゼーションに続いてディエルス・アルダー反応が観察された産物分布を説明していることが示されています.

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