Jove
Visualize
お問い合わせ
JoVE
x logofacebook logolinkedin logoyoutube logo
JoVEについて
概要リーダーシップブログJoVEヘルプセンター
著者向け
出版プロセス編集委員会範囲と方針査読よくある質問投稿
図書館員向け
推薦の声購読アクセスリソース図書館諮問委員会よくある質問
研究
JoVE JournalMethods CollectionsJoVE Encyclopedia of Experimentsアーカイブ
教育
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab Manual教員リソースセンター教員サイト
利用規約
プライバシーポリシー
ポリシー

関連する概念動画

Oxidative Cleavage of Alkenes: Ozonolysis01:46

Oxidative Cleavage of Alkenes: Ozonolysis

In ozonolysis, ozone is used to cleave a carbon–carbon double bond to form aldehydes and ketones, or carboxylic acids, depending on the work-up.
Ozone is a symmetrical bent molecule stabilized by a resonance structure.
Exceptions to the Octet Rule02:55

Exceptions to the Octet Rule

Many covalent molecules have central atoms that do not have eight electrons in their Lewis structures. These molecules fall into three categories:
Phase I Reactions: Oxidation of Carbon-Heteroatom and Miscellaneous Systems01:15

Phase I Reactions: Oxidation of Carbon-Heteroatom and Miscellaneous Systems

Oxidative reactions are pivotal in metabolizing numerous compounds, including pharmaceutical drugs. These reactions often occur in carbon-heteroatom systems, such as carbon-nitrogen, carbon-sulfur, and carbon-oxygen.
In carbon-nitrogen systems, aliphatic and aromatic amines can undergo oxidative reactions. Secondary and tertiary amines, like those found in tricyclic antidepressants, can undergo N-dealkylation, a process that involves the oxidation of the alkyl group. In addition, oxidative...
Frost Circles for Different Conjugated Systems01:18

Frost Circles for Different Conjugated Systems

The inscribed polygon method is consistent with Hückel’s 4n + 2 rule and helps to learn whether the given cyclic compound is aromatic or not. The compound is stable and aromatic if every bonding molecular orbital (MO) is completely filled with a pair of electrons. However, if the non-bonding or antibonding orbitals are filled with electrons, the compound is unstable and not aromatic. Consider the Frost circle diagrams for cycloalkenes containing 4 to 8 carbons.
Mass Spectrometry: Cycloalkane Fragmentation01:05

Mass Spectrometry: Cycloalkane Fragmentation

In mass spectrometry, cycloalkanes exhibit distinct fragmentation patterns due to the inherent stability of their molecular ions compared to linear or branched alkanes. The ring structure of cycloalkanes provides additional stability to the molecular ions, often resulting in prominent ion peaks in the mass spectrum.
For example, cyclohexane molecular ions have a mass-to-charge ratio (m/z) of 84, which tends to produce a stronger signal than linear alkanes like hexane. This stability comes from...
Mass Spectrometry: Molecular Fragmentation Overview01:20

Mass Spectrometry: Molecular Fragmentation Overview

The ionization of a molecule into a molecular ion inside the mass spectrometer causes instability in the molecule's structure due to the loss of an electron. This eventually leads to the fragmentation or breaking of some bonds in the molecule. The fragmentation occurs predominantly at specific bonds to yield relatively stable fragments.
One type of fragmentation pattern is the cleavage of a single bond in the molecular ion. The cleavage leads to a radical and a cation. The cleavage can occur at...

こちらも読む

関連記事

共著者、ジャーナル、引用グラフによってこの研究に関連する記事。

並び替え
Same author

Use of virtual meeting and survey technology to assess Covid-19-related mental well-being of healthcare workers.

Ethics, medicine, and public health·2022
Same author

Surface-induced dissociation in tandem quadrupole mass spectrometers: A comparison of three designs.

Journal of the American Society for Mass Spectrometry·2013
Same author

Mass spectrometry and fullerenes.

Journal of the American Society for Mass Spectrometry·2013
Same author

Laser desorption-membrane introduction mass spectrometry.

Analytical chemistry·2011
Same author

Platform for establishing interlaboratory reproducibility of selected reaction monitoring-based mass spectrometry peptide assays.

Journal of proteome research·2010
Same author

Reproducibility and sensitivity of polarized light scattering for identifying bacterial suspensions.

Applied optics·2010

関連する実験動画

Updated: Jul 12, 2026

Computation of Atmospheric Concentrations of Molecular Clusters from ab initio Thermochemistry
12:11

Computation of Atmospheric Concentrations of Molecular Clusters from ab initio Thermochemistry

Published on: April 8, 2020

フラーレン-オゾン反応による大きな奇数炭素集群.

S W McElvany, J H Callahan, M M Ross

    Science (New York, N.Y.)
    |June 11, 1993
    PubMed
    まとめ

    C119,C129,C139のような奇数の炭素群が発見されました. これらのフルレンの誘導体は,オゾン反応によるフルレンの機能化のための新しい方法を示唆しています.

    科学分野:

    • 化学 化学は化学です.
    • マテリアルサイエンス 材料科学

    背景:

    • C60やC70のようなフルレーンは,独特のケージ状の構造を持つ炭素のアロトロップである.
    • フラーレンのニキビとトロウエンの抽出物は,フラーレンの研究のための一般的な情報源です.
    • オゾン反応は,炭素構造を変更することが知られている.

    研究 の 目的:

    • 奇数炭素群の形成と性質を調査する.
    • フラーレンの反応におけるオゾンの役割を調査する.
    • 完全な機能化のための潜在的な新しい経路を特定する.

    主な方法:

    • フラーレン・ソート抽出物の質量スペクトロメトリー分析.
    • オゾン-フルレレン反応製品の分析.
    • ガス相イオンの特性について.

    主要な成果:

    • 奇数炭素群の観測:C119,C129,C139について
    • 特定された特定の形成経路:オゾンからC119 - C60,オゾンからC139 - C70,そしてオゾンからC60/C70) の反応から3つ.
    • これらのクラスターは,フルレノに類似した,安定したガス相イオンとして振る舞い,二重体マイナス1個の炭素原子を表します.

    さらに関連する動画

    Preparation of a Corannulene-functionalized Hexahelicene by Copper(I)-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
    09:35

    Preparation of a Corannulene-functionalized Hexahelicene by Copper(I)-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units

    Published on: September 18, 2016

    Spatial Separation of Molecular Conformers and Clusters
    10:37

    Spatial Separation of Molecular Conformers and Clusters

    Published on: January 9, 2014

    関連する実験動画

    Last Updated: Jul 12, 2026

    Computation of Atmospheric Concentrations of Molecular Clusters from ab initio Thermochemistry
    12:11

    Computation of Atmospheric Concentrations of Molecular Clusters from ab initio Thermochemistry

    Published on: April 8, 2020

    Preparation of a Corannulene-functionalized Hexahelicene by Copper(I)-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
    09:35

    Preparation of a Corannulene-functionalized Hexahelicene by Copper(I)-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units

    Published on: September 18, 2016

    Spatial Separation of Molecular Conformers and Clusters
    10:37

    Spatial Separation of Molecular Conformers and Clusters

    Published on: January 9, 2014

    結論:

    • この研究は,フルレンの誘導のための新しい経路を明らかにしています.
    • オゾンで触媒化されたケージ開き反応は,機能化されたフルレレンを合成するための新しい方法を提供します.
    • これらの奇数クラスターの発見は,既知のフルレンの家族とその反応性を拡張します.