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Gas Solubility01:31

Gas Solubility

Gas solubility in liquids forms liquid-gas solutions, such as soft drinks, where carbon dioxide is dissolved in water, and the ocean, where the solubility of oxygen and carbon dioxide supports marine life. The ability of oceans to dissolve gases impacts weather conditions in the troposphere.However, gas-liquid interactions vary. For instance, hydrogen chloride gas is highly soluble in water, while oxygen's solubility is much lower. Because these solutions are non-ideal, Raoult’s law, which...
Physical Properties Affecting Solubility02:19

Physical Properties Affecting Solubility

Solutions of Gases in Liquids
As for any solution, the solubility of a gas in a liquid is affected by the attractive intermolecular forces between solute and solvent species. Unlike solid and liquid solutes, however, there is no solute-solute intermolecular attraction to overcome when a gaseous solute dissolves in a liquid solvent since the atoms or molecules comprising a gas are far separated and experience negligible interactions. Consequently, solute-solvent interactions are the sole...
Molecular Comparison of Gases, Liquids, and Solids02:26

Molecular Comparison of Gases, Liquids, and Solids

Particles in a solid are tightly packed together (fixed shape) and often arranged in a regular pattern; in a liquid, they are close together with no regular arrangement (no fixed shape); in a gas, they are far apart with no regular arrangement (no fixed shape). Particles in a solid vibrate about fixed positions (cannot flow) and do not generally move in relation to one another; in a liquid, they move past each other (can flow) but remain in essentially constant contact; in a gas, they move...
Solubility03:00

Solubility

Solution, Solubility, and Solubility Equilibrium
A solution is a homogeneous mixture composed of a solvent, the major component, and a solute, the minor component. The physical state of a solution—solid, liquid, or gas—is typically the same as that of the solvent. Solute concentrations are often described with qualitative terms such as dilute (of relatively low concentration) and concentrated (of relatively high concentration).
In a solution, the solute particles (molecules, atoms, and/or ions)...
Physical Principles Governing Gas Exchange01:16

Physical Principles Governing Gas Exchange

Gas behavior plays a vital role in understanding bodily processes such as external and internal respiration. External respiration involves the diffusion of oxygen into the blood and carbon dioxide out of it in the lungs. In contrast, internal respiration happens in body tissues, where these gases move in opposite directions.
Gas Laws Governing Respiration
The behavior of gases is guided by Dalton's Law of partial pressures and Henry's Law.
Dalton's Law asserts that the total pressure exerted by...
Chemical and Solubility Equilibria02:21

Chemical and Solubility Equilibria

The free energy change associated with dissolving a solute in a liter of solvent is called the free energy of a solution, ΔGsolution. The overall ΔGsolution is expressed as the balance of ΔGinteraction against the always-favorable free-energy of mixing, ΔGmixing. Solution formation is favorable if  ΔGsolution is less than zero, whereas it is unfavorable if ΔGsolution is greater than zero. In short, for a solution to form and complete dissolution to take place, the Gibbs energy change must be...

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Updated: Jul 12, 2026

Fizzy Extraction of Volatile Organic Compounds Combined with Atmospheric Pressure Chemical Ionization Quadrupole Mass Spectrometry
08:10

Fizzy Extraction of Volatile Organic Compounds Combined with Atmospheric Pressure Chemical Ionization Quadrupole Mass Spectrometry

Published on: July 14, 2017

なぜガスが液体中に溶けるのか.

G L Pollack

    Science (New York, N.Y.)
    |March 15, 1991
    PubMed
    まとめ

    最初の原理から溶解性を予測することは依然として困難です. この研究では,有機溶媒におけるクセノン溶解性実験,架け橋理論および現在の理解のギャップを特定するための実験を紹介しています.

    科学分野:

    • 熱力学は熱力学である.
    • 統計力学 統計力学 統計力学
    • 物理化学 物理化学

    背景:

    • 熱力学と統計力学は,溶解性の理論的枠組みを提供する.
    • 最初の原理から実際のシステムに対する溶解性の定量的な予測は難しい.

    研究 の 目的:

    • 試作溶液-溶媒系における溶解性実験の結果を提示する.
    • これらの溶解性が,分子第一原理からどの程度理解できるかを評価する.
    • 現在の予測モデルにおける限界や欠けている要素について議論する.

    主な方法:

    • 単純な有機溶媒におけるクセノン溶解性の実験的決定.
    • 実験データと,分子第一原理から派生した理論的予測を比較する.

    主要な成果:

    • 特定の有機溶媒システムについて提示されたクセノン溶解度データ.
    • 合意の分析と実験結果と理論的予測の間の不一致.
    • 現在の第一原則アプローチが不足している分野を特定する.

    結論:

    • 実験的な溶解度データは,理論的なモデルのための基準となる.

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  • 最初の原理から溶解性を理解するには,さらなる開発が必要です.
  • 現在の理論のギャップは,物理化学における将来の研究の方向性を強調しています.