まとめ
高圧実験では,オリヴィンとスピネル鉱物は,極端な条件下で不均衡に酸化マグネシウムと鉄の酸化物とステショビット (高圧形式のシリカ) に変化することを示しています. これは,地球深層の圧力下での新しい鉱物相変換を明らかにします.
科学分野:
- 地質化学 地質化学
- ミネラル物理学 ミネラル物理学
- 高圧科学 高圧科学とは
背景:
- オリバインとスピネルは,地球のマントルの主要な岩石形成鉱物です.
- 極端な圧力や温度下での彼らの行動を理解することは,地球深層の地力学にとって極めて重要です.
研究 の 目的:
- オリヴィンとスピネルの相変換を,高圧と高温で研究する.
- これらの鉱物における不均衡反応の産物を決定する.
主な方法:
- オリヴィンとスピネルの試料は,異なる組成で,ダイヤモンドのアンビルセルを使用して,最大250キロバーの圧力をかけました.
- 連続波のYAGレーザーを用いて~1700°Cまでのインシトゥー加熱を達成しました.
- 温度測定は,光学ピロメトリーを用いて行われました.
- 試料の組成を冷却と卸し後に分析するために,X線 difrraction が使用されました.
主要な成果:
- X線 difraktion パターンは,オリヴィンとスピネルが適用された条件下では不釣り合いであることを確認しました.
- 観察された製品は (Mg, Fe) Oとstishovite (SiO(s)) と特定されました.
結論:
- オリビンとスピネルは,250キロバーを超える圧力と約1700°Cの温度で (Mg, Fe) Oとスティショビットに不釣り合いを経験します.
- これらの発見は,鉱物の安定性と地球の深い内部の変容についての洞察を提供します.
関連する概念動画
Valence Bond Theory
Coordination compounds and complexes exhibit different colors, geometries, and magnetic behavior, depending on the metal atom/ion and ligands from which they are composed. In an attempt to explain the bonding and structure of coordination complexes, Linus Pauling proposed the valence bond theory, or VBT, using the concepts of hybridization and the overlapping of the atomic orbitals. According to VBT, the central metal atom or ion (Lewis acid) hybridizes to provide empty orbitals of suitable...
Colors and Magnetism
Color in Coordination Complexes
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human eye.
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human eye.
Ferromagnetism
Materials like iron, nickel, and cobalt consist of magnetic domains, within which the magnetic dipoles are arranged parallel to each other. The magnetic dipoles are rigidly aligned in the same direction within a domain by quantum mechanical coupling among the atoms. This coupling is so strong that even thermal agitation at room temperature cannot break it. The result is that each domain has a net dipole moment. However, some materials have weaker coupling, and are ferromagnetic at lower...
Formation of Complex Ions
A type of Lewis acid-base chemistry involves the formation of a complex ion (or a coordination complex) comprising a central atom, typically a transition metal cation, surrounded by ions or molecules called ligands. These ligands can be neutral molecules like H2O or NH3, or ions such as CN− or OH−. Often, the ligands act as Lewis bases, donating a pair of electrons to the central atom. These types of Lewis acid-base reactions are examples of a broad subdiscipline called coordination...
Spin–Spin Coupling: Two-Bond Coupling (Geminal Coupling)
Two NMR-active nuclei bonded to a central atom can be involved in geminal or two-bond coupling. Geminal coupling is commonly seen between diastereotopic protons in chiral molecules and unsymmetrical alkenes, among others.
The central atom need not be NMR-active because its electrons are affected by the electron polarization of the spin-active atoms. However, spin information is transmitted less effectively than in one-bond coupling, and 2J values are usually weaker than 1J values. The energy of...
The central atom need not be NMR-active because its electrons are affected by the electron polarization of the spin-active atoms. However, spin information is transmitted less effectively than in one-bond coupling, and 2J values are usually weaker than 1J values. The energy of...
Washing, Drying, and Ignition of Precipitates
After filtration, the precipitate is washed to remove coprecipitated impurities and any remaining mother liquor. Colloidal precipitates, such as silver chloride, are washed with an electrolyte (such as dilute nitric acid) to prevent the peptization of the precipitate. In the case of slightly soluble precipitates, the wash solution contains a common ion to reduce solubility. Lead sulfate, which is slightly soluble in water, is washed with dilute sulfuric acid. Similarly, wash solutions may be...


