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Updated: Jul 11, 2026

Synthesis of Information-bearing Peptoids and their Sequence-directed Dynamic Covalent Self-assembly
09:34

Synthesis of Information-bearing Peptoids and their Sequence-directed Dynamic Covalent Self-assembly

Published on: February 6, 2020

アリアミンで置換されたオリゴ ((梯子型ペンタフェニレン):ブリッジ化されたリドックスセンター間の電子通信

Gang Zhou1, Martin Baumgarten, Klaus Müllen

  • 1Max-Planck-Institute for Polymer Research, Ackermannweg 10, D-55128 Mainz, Germany.

Journal of the American Chemical Society
|September 21, 2007
PubMed
まとめ

異なる橋長を持つ新しいオリゴ (梯子型ペンタフェニレン) が合成されました. 短いブリッジは電荷の移転と通信を可能にし,長いブリッジは電荷を局所化し,光電子特性に影響を与えます.

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Ladder Diagrams: Redox Equilibria

Ladder diagrams are useful tools for understanding redox equilibrium reactions, especially the effects of concentration changes on the electrochemical potential of the reaction. The vertical axis in the redox ladder diagrams represents the electrochemical potential, E. The area of predominance is demarcated using the Nernst equation.
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The reaction of weakly electrophilic aryldiazonium (also called arenediazonium) salts with highly activated aromatic compounds leads to the formation of products with an —N=N— link, called an azo linkage. This reaction, presented in Figure 1, is known as diazo coupling and occurs without the loss of the nitrogen atoms of the aryldiazonium salt. Highly activated aromatic compounds such as phenols or arylamines favor the diazo coupling reaction. The coupling generally occurs at the para position.
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