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Updated: Jul 11, 2026

Enzymatic Cascade Reactions for the Synthesis of Chiral Amino Alcohols from L-lysine
09:14

Enzymatic Cascade Reactions for the Synthesis of Chiral Amino Alcohols from L-lysine

Published on: February 16, 2018

炭酸塩を含む酵素メカニズムにおける合成効率:アリストロケーンシンタゼ

Rudolf K Allemann1, Neil J Young, Shuhua Ma

  • 1School of Chemistry, Cardiff University, Park Place, Cardiff, CF10 3AT, U.K. allemannrk@cf.ac.uk

Journal of the American Chemical Society
|October 9, 2007
PubMed
まとめ

アリストロケーン合成によるファルネシルピロホスファート (FPP) の (+) -アリストロケーンへのサイクル化の新しいメカニズムには,以前のモデルとは異なる直接の分子内プロトン転送が含まれています. この陽子転送は酵素によって促進され,活性化エネルギーを低下させ,基板特異性を説明します.

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