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分子間陽子転移反応における水の役割について

Bradley J Siwick1, Huib J Bakker

  • 1Departments of Physics and Chemistry, McGill University, 3600 University Street, Montreal, Quebec, Canada. bradley.siwick@mcgill.ca

Journal of the American Chemical Society
|October 16, 2007
PubMed
まとめ

8-hydroxy-1,3,6-pyrenetrisulfonic acid (HPTS) とアセテートとの間のプロトン転送には,複数の水分子が関与しています. 塩基濃度が高い場合,陽子伝搬は,拡散ではなく,グロッツスのような伝導によって制限されます.

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