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Updated: Jul 10, 2026

Self-assembling Morphologies Obtained from Helical Polycarbodiimide Copolymers and Their Triazole Derivatives
09:22

Self-assembling Morphologies Obtained from Helical Polycarbodiimide Copolymers and Their Triazole Derivatives

Published on: February 7, 2017

副鎖の障害とアルキル置換,結合オリゴマーの相変異. P3ATにおけるサイドチェーンの融解との関係

M David Curtis1, John I Nanos, Hyunsik Moon

  • 1Department of Chemistry and the Macromolecular Science and Engineering Program, The University of Michigan, Ann Arbor, Michigan 48109, USA. mdcurtis@umich.edu

Journal of the American Chemical Society
|November 9, 2007
PubMed
まとめ

アルキル置換されたビチアゾールオリゴーマーの中には,融点以下で結晶・結晶相移行 (アルファ・ベータ) を示すものもあります. この移行は,n-パラフィンやポリ−3-アルキルチオフェンと類似した,ガウチ欠陥の増加を伴う.

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