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Updated: Jul 7, 2026

Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex
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1,2-ジフェニルヒドラジンを含むジルコニウム (((IV)) リドックス活性リガンド複合体の触媒反応性

Karen J Blackmore1, Neetu Lal, Joseph W Ziller

  • 1Department of Chemistry, University of California, Irvine, California 92697, USA.

Journal of the American Chemical Society
|February 13, 2008
PubMed
まとめ

酸化還元活性リガンドを含むジルコニウム複合体は,予期せぬ反応性を示す. この研究は,ハロゲン添加と1,2-ディフェニルヒドラジンの触媒的不均衡により,アニリンとアゾベンゼンを形成するリガンドの2電子酸化を明らかにしています.

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