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Updated: Jul 7, 2026

Preparation of a Corannulene-functionalized Hexahelicene by Copper(I)-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
09:35

Preparation of a Corannulene-functionalized Hexahelicene by Copper(I)-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units

Published on: September 18, 2016

銅媒介酸化脱オロマ化/[4 + 2]二酸化カスケードを用いたビサイクロ[2.2.2]オクテノンのエナチオセレクティブ合成

Suwei Dong1, Jianglong Zhu, John A Porco

  • 1Department of Chemistry and Center for Chemical Methodology and Library Development (CMLD-BU), Boston University, Boston, Massachusetts 02215, USA.

Journal of the American Chemical Society
|February 13, 2008
PubMed
まとめ

新しい銅触媒反応により,複雑なビサイクロ[2.2.2]オクテノンの構造が生成されます. この方法は, (+) -aquaticol.の総合成とステレオ化学の修正に使用されました.

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