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Updated: Jul 6, 2026

Ion Mobility-Mass Spectrometry Techniques for Determining the Structure and Mechanisms of Metal Ion Recognition and Redox Activity of Metal Binding Oligopeptides
11:04

Ion Mobility-Mass Spectrometry Techniques for Determining the Structure and Mechanisms of Metal Ion Recognition and Redox Activity of Metal Binding Oligopeptides

Published on: September 7, 2019

アニオンの電荷は,アルミニウムとマグネシウムフッ素のトランジション状態のアナログのフォスフォリル転送酵素の幾何学よりも優先されます

Nicola J Baxter1, G Michael Blackburn, James P Marston

  • 1Department of Molecular Biology and Biotechnology, University of Sheffield, Sheffield S10 2TN, United Kingdom.

Journal of the American Chemical Society
|March 6, 2008
PubMed
まとめ

金属フッ化物複合体は,酵素触媒の理解に不可欠である. この研究では,pHがフッ素の調整に影響し,マグネシウムフッ素 (MgF3-) がより高いpHでアルミニウムフッ素 (AlF4-) を置き換え,酵素抑制と生理学的効果に影響することを明らかにしました.

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Vibrational Spectra of a N719-Chromophore/Titania Interface from Empirical-Potential Molecular-Dynamics Simulation, Solvated by a Room Temperature Ionic Liquid08:54

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All ortho–para directors, excluding halogens, are activating groups. These groups donate electrons to the ring, making the ring carbons electron-rich. Consequently, the reactivity of the aromatic ring towards electrophilic substitution increases. For instance, the nitration of anisole is about 10,000 times faster than the nitration of benzene. The electron-donating effect of the methoxy group in anisole activates the ortho and para positions on the ring and stabilizes the corresponding...
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