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Updated: Jul 6, 2026

Isolating Free Carbenes, their Mixed Dimers and Organic Radicals
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Isolating Free Carbenes, their Mixed Dimers and Organic Radicals

Published on: April 19, 2019

クロロカルベン/アルケンの添加反応におけるエンタルピー対エントロピー

Robert A Moss1, Lei Wang, Min Zhang

  • 1Department of Chemistry and Chemical Biology, Rutgers, The State University of New Jersey, New Brunswick, New Jersey 08903, USA. moss@rutchem.rutgers.edu

Journal of the American Chemical Society
|April 9, 2008
PubMed
まとめ

この研究では,アルケンの添加物であるジクロロカルベン (CCl2) とクロロフッ素カルベン (CClF) の活性化パラメータを測定した. 結果は,反応障壁に対するエントロピックとエントロピックの貢献が異なることを示し,高度に反応性のあるアルケンの場合,エントロピック要因が優位である.

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