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Updated: Jul 6, 2026

Experimental Approaches for the Synthesis of Low-Valent Metal-Organic Frameworks from Multitopic Phosphine Linkers
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Published on: May 12, 2023

微細な金属有機構造で,Mn2+の調整部位が露出している,サイズ選択によるルイス酸触媒

Satoshi Horike1, Mircea Dinca, Kentaro Tamaki

  • 1Department of Chemistry, University of California, Berkeley, California 94720, USA.

Journal of the American Chemical Society
|April 11, 2008
PubMed
まとめ

新しい金属有機構造体であるMn3[(Mn4Cl) 3BTT8(CH3OH) [10]2は,シアノシル化とムカイヤマ-アルドール反応を効率的に触媒化する. このルイス酸触媒は,高収量とサイズ選択性を実証し,既存の金属有機フレームワークの性能を上回る.

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