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Updated: Jul 5, 2026

Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex
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Published on: July 27, 2022

D3h C78 (金属) フルレンの化学反応性:Sc3N封入によって誘発された地域選択性変化

Sílvia Osuna1, Marcel Swart, Josep M Campanera

  • 1Institut de Química Computacional and Departament de Química, Universitat de Girona, Campus Montilivi, 17071 Girona, Catalonia, Spain.

Journal of the American Chemical Society
|April 17, 2008
PubMed
まとめ

フラーレンの内部にメタルニトリドのクラスタを封じ込めると,そのエクソヘドール反応性が著しく変化します. 内部型金属フルルレンに対するディエルス・アルダー反応では,反応部位が変化したため,フリーフルレンと比べて異なる製品が得られます.

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