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Updated: Jul 5, 2026

[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
09:12

[(DPEPhos)(bcp)Cu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst

Published on: May 21, 2019

水溶液中の二核銅複合体による過酸化水素と酸化酸素の活性化:内部電子移転によって開始されたヒドロキシルラジカル生成

Qing Zhu1, Yuxiang Lian, Sunita Thyagarajan

  • 1Department of Chemistry and Biochemistry, University of Maryland, College Park, Maryland 20742, USA.

Journal of the American Chemical Society
|April 25, 2008
PubMed
まとめ

二核銅 (CuII2Nn) 複合体 (CuII2Nn) は,ヒドロキシルまたはリガンド基のラジカルを生成することによって選択的にDNAを割ります. これは,金属-ペロキソ介質との直接反応ではなく,分子内電子伝送メカニズムによって起こります.

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