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Isolating Free Carbenes, their Mixed Dimers and Organic Radicals
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カーベンのシステム間交差率に対する溶媒の影響

Jin Wang1, Jacek Kubicki, Huolei Peng

  • 1Department of Chemistry, The Ohio State University, 100 West 18th Avenue, Columbus, Ohio 43210, USA.

Journal of the American Chemical Society
|April 25, 2008
PubMed
まとめ

調整溶媒は,カーベンのシステム間交差 (ISC) 率に影響を与える. 極性だけでなく,特定の溶媒の相互作用が,単一カルベンを安定させることで,ISCに影響を与え,放射能のない移行の黄金律を明らかに違反します.

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