リュテニウムテルピリジン-4'-カルボキシラート複合体における簡単な協調されたプロトン-電子移転は,酸化還元部位と塩基部位との間の距離が長い

Virginia W Manner1, Antonio G Dipasquale, James M Mayer

  • 1Department of Chemistry, University of Washington, Seattle, Washington 98195-1700, USA.

まとめ

テルピリジン-4'-炭酸塩酸リガンドを含むルテニウム複合体を合成した. Ru (III) 複合体は,電子と陽子の移転を容易にし,リドックスセンターの間の大きな距離にもかかわらず,水素原子移転反応を模倣します.

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