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Updated: Jul 4, 2026

Facile Preparation of (2Z,4E)-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
06:46

Facile Preparation of (2Z,4E)-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate

Published on: June 21, 2017

エナチオセレクティブ クレイゼン再配列は,水素結合ドナー触媒を用いて行われます

Christopher Uyeda1, Eric N Jacobsen

  • 1Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, Massachusetts 02138, USA.

Journal of the American Chemical Society
|June 26, 2008
PubMed
まとめ

新しいグアニジニウムイオン触媒は,アルリルビニルエーテルにおける[3,3]-シグマトロピク再配置を効果的に促進する. C2対称派生体は,エステル置換基板に対する高度なエナチオセレクティブの触媒的なクライスン再配置を達成します.

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