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Updated: Jul 4, 2026

Synthesis of Hypervalent Iodonium Alkynyl Triflates for the Application of Generating Cyanocarbenes
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Published on: September 8, 2013

アルケンの水酸化は,イリジウムシリレン複合体によるカチオンの水素置換による水酸化である

Elisa Calimano1, T Don Tilley

  • 1Department of Chemistry, University of California, Berkeley, California 94720, USA.

Journal of the American Chemical Society
|June 28, 2008
PubMed
まとめ

新型カチオンイリジウムシリレン複合体が合成され,アルケーンとの反応性を実証し,新しいSi-C結合を形成しました. この複合体は,また,高抗マルコヴニコフニコフ選択性を持つシルアンのアルケンの水酸化を効率的に触媒化する.

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